Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Types 304, 304l and 304h are the most versatile and widely used of all the stainless steels. Astm g123 002015 standard test method for evaluating. Chemical and petrochemical processing industries use the alloys for heat exchangers and other piping systems in nitric acid media especially where resistance to chloride stresscorrosion cracking is required. Stress corrosion cracking resistance of super 304h stainless steel was. May 27, 2011 for austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. Some 95% of 316l chemical plant equipment failures may be attributed to chloride scc. Ctlstress corrosion cracking of a stainless steel pipeline. Stress corrosion cracking scc can occur in austenitic stainless steels when they are stressed in tension in chloride environments at temperatures in excess of about 60c. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Chloride stress corrosion cracking in austenitic stainless. The scc behavior of this super 304h stainless steel has not been widely reported.
The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Stress corrosion cracking of austenitic stainless steels in chloride. Chloride stress corrosion cracking in austenitic stainless steel. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Chloride induced stress corrosion cracking of type 304 and. Stainless steel 304, 304l, 304h shims supplier, manufacturer. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design.
For this reason, many products have dual certification as 304304l and 304. Stress corrosion cracking scc is a common mode of failure. Stress corrosion cracking in a brewery paul mueller company. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Small differences between samples such as heattoheat variations of the same grade are not likely to be detected. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of practice g36. Alloy c276 nickel alloy plate has excellent corrosion resistance in both oxidizing and reducing environments. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Although no stainless steel grade is totally immune to chloride scc, the relative.
For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Chloride stress corrosion cracking and 316 stainless steel. Recently, a new type of austenitic stainless steels called super304h stainless steel, containing 3% copper is being adopted for super critical boiler applications. Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stress corrosion cracking than the standard 300 series and standard duplex stainless steels. The combination of the high molybdenum and chromium content, along with the addition of tungsten, make alloy c276 nickel alloy plate highly resistant to chloride stress corrosion cracking, pitting, crevice corrosion and general corrosion. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. However, it is subject to carbide precipitation in the heat affected zone haz of welds. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Therefore, standard grades such as 304304l and 316316l are very. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 600c. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Heattreating equipment such as baskets, trays, and fixtures employ stainless steel 304304l304h shims.
Stress corrosion cracking behaviour of gas tungsten arc welded. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Localized corrosion and stress corrosion cracking of stainless steels. Through controlled addition of nitrogen to alloy 304, 304l can meet the same mechanical properties as 304. Chloride stress corrosion cracking is the most likely life limiting failure with austenitic. Stress corrosion cracking behaviour of gas tungsten arc. It has general corrosion resistance similar to the low carbon 304304l. Three general classifications are used to identify stainless steels. Design guidelines for the selection and use of stainless steel nidl distributed by. For austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. This means that all environments do not cause scc on all of the alloys. Stress corrosion cracking of a stainless steel pipeline. The generalpurpose grade, widely used where good formability and corrosion resistance are required. Transgranular stress corrosion cracking of 304l stainless.
Metalenvironment combinations susceptible to cracking are specific. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Direct correlations are made between the extent of chromium depletion at grain boundaries and intergranular stress corrosion cracking igscc of 304 stainless steel during slowstrainrate ssr tensile tests in 288 c airsaturated water. Come to us for your 304304l304h stainless steel pipe alloy 304l is a low carbon austenitic stainless steel. Stress corrosion cracking scc the alloys 304, 304l, and 304h are the most susceptible of the austenitic stainless steels to stress corrosion cracking scc in halides because of their relatively low nickel content. The similarities and differences in the stress corrosion cracking response of ferritic and austenitic stainless steels in chloride solutions will be examined. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment. Reference is often made to stainless steel in the singular sense as if it were one material. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking scc is a common mode of failure encountered in boiler components especially in austenitic stainless steel tubes at high temperature and in chloriderich water environment. The final, definitive version of this document can be found online at. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Stress corrosion cracking susceptibility of super 304h parent metal and gas tungsten arc gta welded joints were studied by constant load tests in. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Features high strength, chloride stress corrosion cracking resistance, lower coefficient of thermal expansion than austenitic stainless steels. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Stress corrosion cracking scc is a common issue with many specialty alloys. Susceptible alloys include 304l, 316l, 321, and 347. Studies on stress corrosion cracking of super 304h austenitic.
Stress corrosion cracking facts and how to reduce the risk. Welding may worsen the stress corrosion cracking susceptibility of the material. Sensitized austenitic stainless steel suffers stress corrosion cracking. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Dual certified 304304h is used as a material of construction up to 1500f. Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stresscorrosion cracking than the standard 300 series and standard duplex stainless steels. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Prevention of external chloride stress corrosion cracking. Stress corrosion cracking of sensitized type 304 stainless. Stress corrosion cracking of type aisi 304 stainless steel. Excellent in a wide range of atmospheric environments and many corrosive media.
Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The alloys 304, 304l, and 304h are the most susceptible of the austenitic stainless steels to stress corrosion cracking scc in halides because of their relatively low nickel content. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. In this chapter, the conditions for the occurrence of scc are first introduced.
Chloride stress corrosion cracking ssina specialty steel. Stress corrosion cracking behaviour of gas tungsten. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Chloride induced stress corrosion cracking of type 304 and 304l. The scc behavior of this super 304h stainless steel has not been widely. Intamet stocks 304 and 304h, the most widely used austenitic stainless steel modified with a controlled carbon chemistry for increased strength to 1500f. Their chemical composition, mechanical properties, weldability and corrosionoxidation resistance provide the best allround performance stainless. Chloride stress corrosion cracking is the most likely life limiting failure with austenitic stainless steel tubing.
Studies on stress corrosion cracking of super 304h. Intergranular stress corrosion cracking of welded steel twi. The influence of chloride concentration and acidity on the occurrence of stress corrosion cracking s. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. Chloride stress corrosion cracking inspectioneering. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
The boiling magnesium chloride test cracks materials with the nickel levels found in relatively resistant austenitic and duplex stainless steels, thus. It can lead to unexpected sudden failure of normally ductile metals. Influence of chromium depletion on intergranular stress. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. Stress corrosion cracking scc is a common mode of failure encountered in boiler components especially in austenitic stainless steel tubes at high temperature and in chloride rich water environment. The stress may be applied, as in a pressure system, or it may be residual arising from cold working operations or welding. Stress corrosion cracking of stainless steels springerlink. An example is hot potable water under heat transfer conditions which permit chlorides to concentrate locally. Stress corrosion cracking of type aisi 304 stainless steel at. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e.
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